Hazard Pictograms and Signal Words

Hazard pictograms provide information on the hazards posed by hazardous substances, mixtures and products containing explosive materials. Signal words are used to describe the extent of the hazard.

Pictograms are graphical representations, which consist of a symbol and additional graphical elements, such as a border, a background pattern or a background colour.

Annex I Part 1 no. 1.2 of the CLP Regulation specifies, that the hazard pictograms have to be diamond-shaped. In addition, a black symbol must appear on a white background in a clearly visible red frame.

Each hazard pictogram must occupy at least one fifteenth of the minimum area of the label, and shall not have an area below 1 cm² (the minimum area).

The nine hazard pictograms for the individual hazard classes, the differentiations of a hazard class and the hazard categories must correspond to the requirements of Annex V and Annex I, section 1.2 of the CLP Regulation. Regarding the symbols and the general format, they must also comply with the following examples.

The hazard pictograms have a coding system along similar lines to the hazard and safety information. All nine of the pictograms are sorted numerically from GHS01 - GHS09.

Number of required pictograms

The number of required pictograms should not overload the label. Therefore, according to Article 26, paragraph 1 of the CLP Regulation, it is necessary to follow a specific ranking order:

  1. If labelling with "GHS01" is required, the use of "GHS02" and "GHS03" is optional
  2. If labelling with "GHS06" is required, "GHS07" does not appear.;
  3. If labelling with "GHS05" is required, "GHS07" for skin and eye irritation does not appear.
  4. If labelling with "GHS08" in combination with H334 (Resp. Sens. 1, 1A, 1B) is required, "GHS07" does not appear in conjunction with H317 (Skin Sens, 1, 1A, 1B), H315 (Skin Irrit. 2) or H319 (Eye Irrit. 2).
  5. If labelling with "GHS02" or “GHS06” is required, the use of "GHS04" is optional.

Information on signal words

The signal word is the part of the label that states the extent of the hazard. Its purpose is to notify the reader of the label of a potential hazard. Differentiation is made between two hazard levels:

  1. Danger: Signal word for severe hazard categories
  2. Warning: Signal word for less severe hazard categories

The CLP Regulation stipulates which signal word is to be assigned and when. The hazard communication tables in Annex I, parts 2 to 5 of the CLP Regulation, detail the required signal words for the individual hazard categories.

Please note the following:

If the classification shows that a signal word should be assigned several times, it will appear only once on the label. If the signal word "Danger" is used, the signal word "Warning" does not appear.

This table provides an overview of the nine hazard pictograms:

Physical hazards

Symbol GHS01: Exploding bomb

PictogramHazard class and hazard category
GHS01

Section 2.1

Unstable explosives
Explosives of Divisions 1.1, 1.2, 1.3, 1.4

Section 2.8

Self-reactive substances and mixtures, Types A, B

Section 2.15

Organic peroxides, types A, B

Symbol GHS02: Flame

PictogramHazard class and hazard category
GHS02

Section 2.2

Flammable gases, hazard categories 1A, 1B

Section 2.3

Aerosols, hazard categories 1, 2

Section 2.6

Flammable liquids, hazard categories 1, 2, 3

Section 2.7

Flammable solids, hazard categories 1, 2

Section 2.8

Self-reactive substances and mixtures, Types B, C, D, E, F

Section 2.9

Pyrophoric liquids, hazard category 1

Section 2.10

Pyrophoric solids, hazard category 1

Section 2.11

Self-heating substances and mixtures, hazard categories 1, 2

Section 2.12

Substances and mixtures, which  in contact with water, emit flammable gases , hazard categories 1, 2, 3

Section 2.15

Organic peroxides, Types B, C, D, E, F

Section 2.17

Desensitised explosives, hazard categories 1,2,3,4

Symbol GHS03: Flame over circle

PictogramHazard class and hazard category
GHS03

Section 2.4

Oxidising gases, hazard category 1

Section 2.13

Oxidising liquids, hazard categories 1, 2, 3

Section 2.14

Oxidising solids, hazard categories 1, 2, 3

Symbol GHS04: Gas cylinder

PictogramHazard class and hazard category
GHS04

Section 2.5

Gases under pressure:

  • compressed gases
  • liquefied gases
  • refrigerated liquefied gases
  • dissolved gases

Symbol GHS05: Corrosion

PictogramHazard class and hazard category
GHS05

Section 2.16

Corrosive to metals, hazard category 1

Specific features of physical hazards

No pictogram is necessary for the following classes and categories of physical hazards:

  • Section 2.1
    Explosives of Division 1.5

  • Section 2.1
    Explosives of Division 1.6

  • Section 2.2
    Flammable gases, hazard category 2

  • Section 2.3
    Aerosols, hazard category 3

  • Section 2.8
    Self-reactive substances and mixtures, Type G

  • Section 2.15
    Organic peroxides, Type G

Health hazards

Symbol GHS06: Skull and crossbones

PictogramHazard class and hazard category
GHS06

Section 3.1

Acute toxicity (oral, dermal, inhalation), hazard categories 1, 2, 3

Symbol GHS05: Corrosion

PictogramHazard class and hazard category
GHS05

Section 3.2

Skin corrosion, hazard categories 1, 1A , 1B, 1C

Section 3.3

Serious eye damage, hazard category 1

Information on labelling with the "Corrosion" symbol

In the case of substances or mixtures, which are toxic if inhaled, GHS05 can also be used in addition to GHS06, if the inhalation data indicate that the toxicity is based on a corrosive effect and EUH071: "Corrosive to the respiratory tract" applies.

Symbol GHS07: Exclamation mark

PictogramHazard class and hazard category
GHS07

Section 3.1

Acute toxicity (oral, dermal, inhalation), hazard category 4

Section 3.2

Skin irritation, hazard category 2

Section 3.3

Eye irritation, hazard category 2

Section 3.4

Skin sensitisation, hazard categories 1, 1A, 1B

Section 3.8

Specific Target Organ Toxicity (single exposure), hazard category 3:

  • Respiratory tract irritation
  • Narcotic effects

Symbol GHS08: Health hazard

PictogramHazard class and hazard category
GHS08

Section 3.4

Respiratory sensitisation, hazard categories 1, 1A, 1B

Section 3.5

Germ cell mutagenicity, hazard categories 1A, 1B, 2

Section 3.6

Carcinogenicity, hazard categories 1A, 1B, 2

Section 3.7

Reproductive toxicity, hazard categories 1A, 1B, 2

Section 3.8

Specific Target Organ Toxicity (single exposure), hazard categories 1, 2

Section 3.9

Specific Target Organ Toxicity (repeated exposure), hazard categories 1, 2

Section 3.10

Aspiration hazard, hazard category 1 

Specific features of health hazards

No pictogram is necessary for the following category of health hazards:

  • Section 3.7
    Reproductive toxicity, effects on or via lactation, additional hazard category
  • Section 3.11
    Endocrine disruption for human health (category 1 and 2)

Environmental hazards

Symbol GHS09: Environment

PictogramHazard class and hazard category
GHS09

Section 4.1

Hazardous to the aquatic environment

  • Acute hazard category: Acute 1

  • Long-term hazard: categories: Chronic 1, Chronic 2

Specific features of environmental hazards

No pictogram is necessary for the following environmental classes and categories:

  • Section 4.1
    Hazardous to aquatic environment - Long-term hazard categories: Chronic 3, Chronic 4
  • Section 4.2
    Endocrine disruption for the environment (category 1 and 2)
  • Section 4.3
    Persistent, Bioaccumulative and Toxic or Very Persistent, Very Bioaccumulative properties
  • Section 4.4
    Persistent, Mobile and Toxic or Very Persistent, Very Mobile properties

Other hazards

Symbol GHS07: Exclamation mark

Pictogram
GHS07

Section 5

Hazardous to the ozone layer, hazard category 1

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Publications

GHS memo card "Hazardous substances compact"

Memocard 2023

(in German)

The GHS "Hazardous substances compact" memo card from the Federal Institute for Occupational Safety and Health (BAuA) contains brief explanations of the GHS symbols which are also easy to understand by those who do not have expertise with chemicals. Information on the codes of conduct with …

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